Synthesis and structure of N-alkoxyhydrazines  and N-alkoxy-N',N',N'-trialkylhydrazinium salts

Please use this identifier to cite or link to this item: http://dspace.sfa.org.ua:80/handle/123456789/1116

Title:	Synthesis and structure of N-alkoxyhydrazines and N-alkoxy-N',N',N'-trialkylhydrazinium salts
Authors:	Shtamburg, Vasiliy G. Shishkin, Oleg V. Zubatyuk, Roman I. Shtamburg, Victor V. Tsygankov, Alexander V. Mazepa, Alexander V. Kadorkina, Gulnara K. Kostyanovsky, Remir G.
Keywords:	GEMINAL SYSTEMS DERIVATIVES AMIDES
Issue Date:	2013
Publisher:	ELSEVIER, RADARWEG 29, 043 NX AMSTERDAM, NETHERLANDS
Citation:	Synthesis and structure of N-alkoxyhydrazines and N-alkoxy-N',N',N'-trialkylhydrazinium salts / Vasiliy G. Shtamburg, Oleg V. Shishkin, Roman I. Zubatyuk and others // Mendeleev Commun. - 2013. - Volume: 23; Issue: 5. - P. 289-291. DOI: 10.1016/j.mencom.2013.09.018
Abstract:	New types of 1,1,1-trialkyl-2-alkoxyhydrazinium chlorides and N-alkoxyhydrazines were obtained by reactions of N-chloro-N-alkoxyureas with trimethylamine or 1,4-diaza[2.2.2]bicyclooctane and by reactions of methyl N-chloro-N-methoxycarbamate with potassium salt of N-acetylbenzenesulfonylamide. The XRD studies of N,N'-bis(methoxycarbonyl)-N,N'-dimethoxyhydrazine, N'-methoxyN'-methoxy carbonyl-N-acetylbenzenesulfonylhydrazide and 1,1,1-trimethyl-2-methoxyhydrazinium perchlorate revealed the pyramidal configuration of the central nitrogen atoms in O–N–N geminal system, unusual elongation of N–N + bond and shortening of N–OMe bond in 1,1,1-trimethyl-2-methoxyhydrazinium perchlorate.
URI:	http://dspace.sfa.org.ua:80/handle/123456789/1116
Appears in Collections:	Наукові публікації

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